|
|
3,5,7,9,11,13,15,17,19-nonaoxoicosanoate <=> 3,5-dioxo-6-[4,5,7-trihydroxy-3-(3-oxobutanoyl)naphthalen-2-yl]hexanoate + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15413
|
|
|
|
S-adenosyl-L-methionine + 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin_C <=> 8-demethyl-8-(2,3-O-dimethyl-alpha-L-rhamnosyl)-tetracenomycin_C + S-adenosyl-L-homocysteine + H+
|
2.1.1.306
8-demethyl-8-(2-methoxy-alpha-L-rhamnosyl)tetracenomycin-C 3'-O-methyltransferase
|
–
|
| |
BRENDA:
BR50858
KEGG:
R10957
MetaCyc:
RXN-15404
|
|
|
|
S-adenosyl-L-methionine + tetracenomycin_D3 <=> tetracenomycin_B3 + S-adenosyl-L-homocysteine
|
2.1.1
|
–
|
| |
MetaCyc:
RXN-15409
|
|
|
|
S-adenosyl-L-methionine + 8-demethyl-8-(2,3-O-dimethyl-alpha-L-rhamnosyl)-tetracenomycin_C <=> 8-demethyl-8-(2,3,4-O-trimethyl-alpha-L-rhamnosyl)-tetracenomycin_C + S-adenosyl-L-homocysteine + H+
|
2.1.1.307
8-demethyl-8-(2,3-dimethoxy-alpha-L-rhamnosyl)tetracenomycin-C 4'-O-methyltransferase
|
–
|
| |
BRENDA:
BR50859
KEGG:
R10958
MetaCyc:
RXN-15403
|
|
|
|
tetracenomycin_F1 + O2 <=> tetracenomycin_D3 + H2O + H+
|
1.13.12.21
tetracenomycin-F1 monooxygenase
|
–
|
| |
BRENDA:
BR50567
KEGG:
R06700
MetaCyc:
RXN-14695
|
|
|
|
S-adenosyl-L-methionine + 8-demethyl-8-(2,3,4-O-trimethyl-alpha-L-rhamnosyl)-tetracenomycin_C <=> elloramycin + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R10959
MetaCyc:
RXN-15402
|
|
|
|
S-adenosyl-L-methionine + tetracenomycin_B3 <=> tetracenomycin_B2 + S-adenosyl-L-homocysteine
|
2.1.1
|
–
|
| |
KEGG:
R06713
MetaCyc:
RXN-15408
|
|
|
|
8-demethyltetracenomycin_C + dTDP-L-rhamnose <=> 8-demethyl-8-alpha-L-rhamnosyl_tetracenomycin_C + dTDP + H+
|
2.4.1.331
8-demethyltetracenomycin C L-rhamnosyltransferase
|
–
|
| |
BRENDA:
BR50871
KEGG:
R10955
MetaCyc:
RXN-15406
|
|
|
|
tetracenomycin_B2 + O2 + NADPH + H+ <=> 8-demethyltetracenomycin_C + H2O + NADP+
|
1.14.13.200
tetracenomycin A2 monooxygenase-dioxygenase
|
–
|
| |
BRENDA:
BS429406
KEGG:
R10954
MetaCyc:
RXN-15407
|
|
|
|
tetracenomycin_F2 <=> tetracenomycin_F1 + H2O
|
4.2.1.154
tetracenomycin F2 cyclase
|
–
|
| |
BRENDA:
BR51058
KEGG:
R06699
MetaCyc:
RXN-15056
|
|
|
|
3,5-dioxo-6-[4,5,7-trihydroxy-3-(3-oxobutanoyl)naphthalen-2-yl]hexanoate <=> tetracenomycin_F2 + H2O
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15412
|
|
|
|
acetyl-CoA + malonyl-CoA + H2O + H+ <=> 3,5,7,9,11,13,15,17,19-nonaoxoicosanoate + CoA + CO2
|
not assigned
|
–
|
| |
MetaCyc:
RXN-11975
|
|
|
|
S-adenosyl-L-methionine + 8-demethyl-8-alpha-L-rhamnosyl_tetracenomycin_C <=> 8-demethyl-8-(2-O-methyl-alpha-L-rhamnosyl)-tetracenomycin_C + S-adenosyl-L-homocysteine + H+
|
2.1.1.305
8-demethyl-8-alpha-L-rhamnosyltetracenomycin-C 2'-O-methyltransferase
|
–
|
| |
BRENDA:
BR50857
KEGG:
R10956
MetaCyc:
RXN-15405
|
|
